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Data from: Evaluating Coordinative Binding Mechanisms through Experimental and Computational Studies of Methoxy-substituted Arylazothioformamide Copper(I) Complexes

UV-Vis spectroscopic titration studies of ATF ligands 6, 8 and 10 with Cu salts were prepared as follows: ligand solutions were prepared to 1.45 x 10-4 M in acetonitrile. 1.2 mL of ATF solution was added to a quartz cuvette. Titrations were performed with Cu halide salts and [N(Bu4)2(µ-I)-Cu2I4] utilizing 1.35 mM stock solutions in acetonitrile and sequentially adding 13 µL (roughly 0.1 equivalent of metal salt) until reaching a metal salt concentration of three equivalents (a final volume of 2.0 mL); [(CH3CN)4CuI]BF4 salts titrations were performed in the same manner as above to a final 1.5 equivalents. Each titration was performed in triplicate.

Data Use:
License: CC-BY 4.0
Recommended Citation: Pradhan, R., Groner, V., Gutman, K. L., Larson, G. E., Kan, Y., Zhang, Q., Heiden, Z., Roll, M., Moberly, J., & Waynant, K. (2022). Data from: Evaluating Coordinative Binding Mechanisms through Experimental and Computational Studies of Methoxy-substituted Arylazothioformamide Copper(I) Complexes [Data set]. University of Idaho. https://doi.org/10.7923/2Z54-2V65

FieldValue
Modified
2022-10-06
Release Date
2022-10-05
Publisher
Identifier
9bf154ff-2d0b-4ccf-8c0b-5775d59a6560
Language
English (United States)
License
Author
Rabina Pradhan, Vincent M. Groner, Kaylaa L. Gutman, Garrett E. Larson, Yuwei Kan, Qiang Zhang, Zachariah M. Heiden, Mark F. Roll, James G. Moberly and Kristopher V. Waynant
Contact Name
Kristopher V. Waynant
Contact Email
Public Access Level
Public
DOI
10.7923/2z54-2v65
Data available on:: 
Wednesday, October 5, 2022